Damages to enemies adjacent from Volatile Poison ignores poison immunity. I don't know whether this is a bug or a feature.
If you have learned Mystic Cunning prodigy, then you first apply the Vunerability Poison and lower the enemy's poison immunity on triggering Apply Poison before trying to apply other poisons, which is very advantageous against enemies normally fully immune to poisons. However, when Toxic Death spreads poisons, Vunerability Poison has no order priority over other poisons. I personally regard this as a bug.
Normally you cannot apply Stoning Poison to enemies already Stoned, but Toxic Death can spread Stoning Poison to them, supposing they're still vulnerable to poisons. This can lead to far longer Stoned period on a single enemy in some situations and can give the player a great advantage, and thus I think this is a bug.
[1.6.7]Toxic Death and Volatile Poison
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- Wyrmic
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